Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)
2020
Utilising normal incidence X-ray standing waves we rigourously scrutinise the “inverted model” as the adsorption structure of free-base tetraphenyl porphyrin on Cu(111). We demonstrate that the iminic N atoms are anchored at near-bridge adsorption sites on the surface displaced laterally by 1.1 ± 0.2 A in excellent agreement with previously published calculations.
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