On the Trapping of Vinylgold Intermediates
2010
An internal aryl-substituted ortho-alkynylphenol and a similar aniline with stoichiometric amounts of N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene-gold tosylate [(IPr)AuOTs] and triethylamine gave the aurated heterocycles as stable intermediates of the corresponding gold(I)-catalysed hydrooxylation and hydroamination reactions. X-ray crystal structure analyses of both products could be obtained. A similar internal alkyl-substituted ortho-alkynylphenol gave only the cycloisomerised product, no aurated intermediate could be detected.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
33
References
128
Citations
NaN
KQI