Sterically Directed Iridium-Catalyzed Hydrosilylation of Alkenes in the Presence of Alkynes.

Jill A. Muchnij,Farai B. Kwaramba,Ronald J. Rahaim

Sterically Directed Iridium-Catalyzed Hydrosilylation of Alkenes in the Presence of Alkynes.

2014

Jill A. Muchnij
Farai B. Kwaramba
Ronald J. Rahaim

In analogy to the hydrosilylation of (Ia), conversion of (Ib) with phenylacetylene or 4-trifluoromethylphenylacetylene yields only the product of anti-Markovnikov addition.

Keywords:

Hydrosilylation
Steric effects
Iridium
Phenylacetylene
Organic chemistry
Chemistry
Catalysis

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