Кинетическая неоднородность титановой каталитической системы при малых конверсиях бутадиена

The study of butadiene polymerization at the catalyst system TiCl4-Al(i-C4H9)3 was carried out in a pulsed mode of the process which ensured a short time of polymerization. It was found that at the time of polymerization 5-6 with titanium catalyst system is kinetically heterogeneous and contains at least three types of polymerization centers.