A reversal phenomenon of enantioface selectivity by the cooperative operation of two chiral catalysts
2011
The reversal phenomenon of enantioface selectivity in the asymmetric addition of diisopropylzinc to aldehydes was observed by mixing two chiral β-amino alcohol catalysts. The opposite enantiomeric product was formed on using a mixture of two chiral catalysts that possess individual enantioselectivity.
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