Formal synthesis of tirandamycin B

Keisuke Takahashi,Rintaro Harada,Yurika Hoshino,Taichi Kusakabe,Susumi Hatakeyama,Keisuke Kato

Formal synthesis of tirandamycin B

2017

Keisuke Takahashi
Rintaro Harada
Yurika Hoshino
Taichi Kusakabe
Susumi Hatakeyama
Keisuke Kato

Abstract A formal synthesis of tirandamycin B is described. The key intermediate is synthesized by Marshall allenyl zinc method, litiofuran coupling, and Achmatowicz reaction to construct the bicyclic core of tirandamycin B.

Keywords:

Tirandamycin B
Tirandamycin
Natural product
Achmatowicz reaction
Organic chemistry
Stereochemistry
Chemistry
Bicyclic molecule
formal synthesis

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