Influence of gold particle size in Au/C catalysts for base-free oxidation of glucose

Abstract A series of gold colloids were prepared and immobilized on commercial activated carbon. The influence of the colloid preparation and stability were studied and related to the gold particle size in the final catalyst. The catalysts show an important activity in the glucose to gluconic acid oxidation reaction, leading to gluconic acid yield close to 90% in base free mild conditions (0.1 MPa O 2 and 40 °C). The size-activity correlation and probable mechanism were also discussed. Finally, the viability of the catalyst was tested by recycling it up to four times.