Transport phenomena in non-uniform gas subjected to laser radiation

2017 
The paper discusses the theory of transport processes in one-component gas located in capillary subjected to resonant laser radiation and both temperature and pressure gradients. The equations for the kinetic coefficients determining heat- and mass transport in the gas are derived on the basis of modified Boltzmann equations for the excited and unexcited particles. The cross kinetic coefficients satisfy the Onsager reciprocity for all Knudsen numbers and laws of gas particles interaction with each other and with boundary surface of the capillary. Analysis of possible non-equilibrium stationary states of first and second order for the one-component gas in the capillary has been developed on the basis of the Prigogine theorem of stationary states. Equations describing the stationary states in Knudsen limit (Kn >> 1) and slip-flow regime (Kn << 1) were derived.
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