Expanding the chemical space for push-pull chromophores by non-concerted [2+2] and [4+2] cycloadditions
2011
Non-concerted [2 + 2] and [4 + 2] cycloadditions between N, N-dimethylanilino- substituted 1,1,2,4,4-pentacyanobuta-1,3-diene and 4-ethynyl-N,N-dimethylaniline are controlled by solvent polarity and provide access to a highly functionalised 6,6-dicyanopentafulvene featuring an intense, low-energy charge-transfer band and to an unusual spirocyclic zwitterion, characterised by X-ray analysis.
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