Dielectric behavior of a thermotropic liquid crystal incorporated in a porous glass
1996
We present measurements of the dielectric constant in a composite system where a thermotropic liquid crystal is incorporated in a silica aerogel. In particular we discuss the observed features in the temperature dependence of /spl epsiv/'/sub L/ (T), the real part of the dielectric constant measured at low frequency. /spl epsiv/'/sub L/ (T) is smaller than the orientational average of the uniaxial anisotropic dielectric constant of the bulk. After rescaling, /spl epsiv/'/sub L/(T) well approximates the temperature dependence of the bulk dielectric behavior. This fact strongly suggests that the silica to liquid crystal interaction is strong and it enables to estimate the total silica surface.
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