Diels—Alder Reactions of 12‐Hydroxy‐9(10→20)‐5aH‐abeo‐abieta‐ 1(10),8(9),12(13)‐triene‐11,14‐dione
2013
12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used.
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