meso-Alkylidenyl dibenzihexaphyrins: Synthesis and protonation studies
2019
The synthesis and characterization of the alkylidenyl-dibenzihexaphyrins bearing four indanedionyl groups at the meso-positions linked via four meso-exocyclic double bonds is reported. Treatment with trifluoroacetic acid at 50 oC leads to C(α)-protonation of the two indanedionyl groups resulting increased macrocyclic conjugation with dramatic red shifted absorption spectra.
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