The crystal and molecular structure of bis(1-methyl-1-phenylhydrazine)dichloro-{1-methyl-1-phenylhydrazido(2–)}vanadium(V) chloride, a complex containing two side-on-co-ordinated hydrazine molecules

John Bultitude,Leslie F. Larkworthy,David C. Povey,Gallienus W. Smith,Jon R. Dilworth,G. Jeffery Leigh

The crystal and molecular structure of bis(1-methyl-1-phenylhydrazine)dichloro-{1-methyl-1-phenylhydrazido(2–)}vanadium(V) chloride, a complex containing two side-on-co-ordinated hydrazine molecules

1986

John Bultitude
Leslie F. Larkworthy
David C. Povey
Gallienus W. Smith
Jon R. Dilworth
G. Jeffery Leigh

The complex [VCl2(H2NNMePh)2(NNMePh)]Cl shows simultaneous co-ordination of side-on hydrazine and end-on hydrazide (2–), and forms a tetranuclear structure via an extensive array of hydrogen bonds.

Keywords:

Hydrazide
Molecule
Chloride
Phenylhydrazine
Inorganic chemistry
Hydrogen bond
X-ray crystallography
Chemistry
Inorganic compound
Vanadium
Organic chemistry

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