Dimerization of Phthalate Ion in Non-Aqueous Solvents
2021
Solutions of tetraethylammonium phthalate in non-aqueous solvents (ethanol,
dimethylsulfoxide, dimethylformamide, and acetonitrile) were studied by
electronic absorption spectroscopy. It was shown that the phthalate anion
dimerizes in acetonitrile and dimethylformamide solutions due to π-stacking, the
experimental equilibrium constants being 550±50 and 900±50, respectively.
Dimerization of the phthalate anion was not observed in ethanol and
dimethylsulfoxide solutions.
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