The characterization of nitrogen-enriched activated carbons by IR, XPS and LSER methods

The aim of this work is to study the efficiency of the nitrogen enrichment by urea of lignites and the induced changes of the adsorptive properties towards volatile organic compounds (VOCs) of the activated carbons derived from these modified precursors. The study is made using infrared and X-ray photoelectrons spectroscopies and the LSER (linear solvation energy relationship) modeling. Four activated lignites derived from the same raw material, original or enriched with nitrogen, are characterized in this way. The effect of the chemical treatment by urea and of the burn-off amount are investigated in term of evolution of the chemistry of the studied materials. The influence of these parameters on the selective behavior of the activated lignites towards two pairs of VOCs is also discussed in terms of molecular interactions using the LSER approach. The results show that the chemical treatment of the raw material is successful, leading to significant enrichment with nitrogen under pyridinic form at the surface of the activated carbons. Moreover, they reveal some selective properties well explained by the LSER analysis and spectroscopic measurements. The selective character of the studied materials is modulated by the duration of the activation step.