A Known Iron(II) Complex in Different Nanosized Particles: Variable-Temperature Raman Study of Its Spin-Crossover Behavior

The spin-crossover (SCO) polymorph B (complex 1) of the known compound [FeII{N(CN)2}2(abpt)2], where abpt is 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole, has been prepared in three different particle sizes averaging ∼300 (sample 1a), ∼80 (sample 1b), and ∼20 nm (sample 1c). Two independent octahedral molecules possessing Fe1 and Fe2 were found to be present in the crystal of B. Magnetostructural relationships had established that at room temperature both FeII sites are in the high-spin state (HS-HS), whereas a decrease in the temperature to 90 K induces the complete high-spin to low-spin conversion of the Fe1 site, with Fe2 remaining in the high-spin state (LS-HS). The three samples have been characterized by elemental analyses, ATR spectra, solution UV/vis spectra (to exclude resonance Raman effects) and powder X-ray diffraction patterns, while their morphological characteristics have been examined by scanning electron microscopy (SEM). The SCO behavior of the originally prepared sample 1a has been moni...