A perylene diimide electron acceptor with a triphenylamine core: promoting photovoltaic performance via hot spin-coating

Perylene diimide (PDI) oligomers, in which the PDI panels were fused together by ethylene bridges, have been emerged as potential alternatives to the parent PDI in organic optoelectronic materials. Meanwhile, triphenylamine (TPA), owing to its facile synthesis, flexible modification, excellent electron donating capability as well as the twisted molecular structure, is commonly employed as the congested core to construct star-shaped electron acceptors and donors for organic solar cells (OSCs). In this contribution, a TPA-cored helical perylene diimide oligomer (PDI2) electron acceptor, namely TPA-3PDI2, was designed and synthesized. Using the commercially available PTB7-Th as electron donor, a power conversion efficiency (PCE) of 5.57% was obtained for the room temperature (RT) spin-coating blends based OSCs. Interestingly, the hot spin-coating blends based OSCs showed higher PCE of 7.04%. The results demonstrate that using PDI2 as a building block to construct star-shaped acceptors is a facile strategy to achieve considerable PCE in OSCs and also, hot spin-coating is a feasible method for morphology optimization.