SPME-GC/MS identification of aroma compounds in rose flowers.

The content and composition of active ingredients and essential oils in medicinal and aromatic plants have been studied for several decades. The volatile compounds in essential oils have been analysed routinely using gas chromatography (GC) since 1966, and with GC coupled to mass spectrometric detection (GC/MS) since 1978.The 13 rose varieties selected for chemical analysis varied for colour, shape and fragrance. The static headspace solid phase microextraction (sHS-SPME) technique recently developed for sample preparation and sample enrichment was used to study the volatile aromatic components.The main volatile compound of a sweet-smelling purple rose was found to be phenyl ethyl alcohol (33–52%). The phenyl ethyl alcohol content of fragrant rose flowers with blackish-purple petals increased continuously from early summer to late autumn (from 17 to 70 %). The dominant aromatic components of the yellow, orange and pink rose flowers were hexanol, hexenyl acetate and benzyl alcohol. Phenyl ethyl alcohol and...