Microwave sintering of nanopowder ZnNb2O6: Densification, microstructure and microwave dielectric properties

High density ZnNb2O6 ceramics were successfully fabricated by microwave sintering of ZnO-Nb2O5 and ZnNb2O6 nanopowclers. Phase formation, microstructure and microwave electrical properties of the microwave sintered (MS) and microwave reaction sintered (MRS) specimens were examined using X-ray diffraction, field emission scanning electron microscopy and microwave dielectric properties measurement. Specimens were sintered in a temperature range from 950 to 1075 degrees C for 30 min at an interval of 25 degrees C using a microwave furnace operated at 245 GHz frequency, 3 kW power. XRD pattern revealed the formation of pure columbite phase of ZnNb2O6. The SEM micrographs show grain growth and reduction in porosity of specimens with the increase in sintering temperature. Good combination of microwave dielectric properties (epsilon(r)similar to 23.6, Q(f)similar to 64,300 GHz and tau(f)similar to 66 ppm/degrees C and epsilon(r)similar to 24, Q(f)similar to 75,800 GHz and tau(f)similar to -64 ppm/ degrees C) was obtained for MS- and MRS-prepared samples at 1000 degrees C and 1050 degrees C for 30 min, respectively. (C) 2014 Elsevier B.V. All rights reserved.