Hydrothermal synthesis and crystal structure of polyoxometalate with the manganic

A supermolecular compound,(H2en)8·[MnMo12O30(PO4)2(HPO4)6]·H2O,was first prepared by hydrothermal synthesis and characterized by elemental analysis,IR,TGA-DSC and single crystal X-ray diffraction.Crystal data:triclinic,space group P-1;a=1.2767 nm,b=1.3625 nm,c=1.4124 nm,α=100.550°,β=109.005°,γ=115.398°,V=1.9429 nm3,Z=1,R1=0.0495,wR2=0.1342.