Geochemical characteristics of carbonaceous chalk near the Cretaceous/Paleogene transition, central Jordan: Strong metal enrichment of redox-sensitive and biophile elements from remineralized calcitic plankton

Abstract Carbonaceous calcitic chalk from a 50-m stratigraphic sample interval (n = 35) of the Maastrichtian-Danian Muwaqqar Chalk Marl (MCM) Formation, Jordan, has elevated concentrations of biophile and/or redox-sensitive trace metals (Mo, Ni, V, U, Cr, Cd, Ag, Se, and P) which indicate enhanced paleo-bioproductivity, biodegradation and remineralization under reducing conditions. Very low concentrations in Mn and Ba suggest a relatively open system for components mobile under reducing conditions. The last 800,000 years to the K/Pg boundary are not exposed in Jordan, but the stratigraphic 20-m-interval below and above the hiatus of the K/Pg transition (n = 8) with 2.6 ± 1.8 wt% organic C is particularly metal-enriched with average bulk-rock contents of 132 ppm Mo, 177 ppm Ni, 363 ppm V, 576 ppm Zn, 39 ppm Se, 1.4 ppm Ag, 106 ppm Cd, 474 ppm Cr. These concentrations are dominantly of authigenous origin, when normalized to PAAS, i.e. 100 % Mo, 100% Ag, 100% Cd, 96% Cr, 95% Ni, 95% Zn, 80% V authigenous, and testify to ≥90% of biodegradation of planktonic debris by anaerobic bacterial activity at or near the seafloor. The depositional environment is euxinic, and Mo/TOC ratios from