Alkylation of Amines Via Tandem Hydroaminomethylation Using Imino-Pyridine Complexes of Rhodium as Catalyst Precursors
2019
Novel cationic Rh(I) imino-pyridine complexes were evaluated as catalyst precursors in the hydroaminomethylation of 1-octene in conjunction with both primary (aniline and benzylamine) and secondary amines (piperidine). These complexes were found to be highly efficient catalysts in mediating a one-pot hydroaminomethylation reaction. High chemoselectivities towards the target secondary and tertiary amines were obtained depending on the reaction components.
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