Zirconium carbonitride pellets by internal sol gel and spark plasma sintering as inert matrix fuel material
2016
Inert matrix fuel is a fuel type where the fissile material is blended with a solid diluent material. In this
work zirconium carbonitride microspheres have been produced by internal sol gel technique, followed
by carbothermal reduction. Material nitride purities in the produced materials ranged from Zr(N0.45C0.55)
to Zr(N0.74C0.26) as determined by X-ray diffraction and application of Vegard's law. The zirconium carbonitride
microspheres have been pelletized by spark plasma sintering (SPS) and by conventional cold
pressing and sintering. In all SPS experiments cohesive pellets were formed. Maximum final density
reached by SPS at 1700 C was 87% theoretical density (TD) compared to 53% TD in conventional sintering
at 1700 C. Pore sizes in all the produced pellets were in the mm scale and no density gradients could be
observed by computer tomography.
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