Direct arylation of imidazo[2,1-b]thiazoles and thiazoles with aryl iodides via CuCl2/PPh3-catalyzed C–H bond functionalization
2015
With PPh3 acting as a ligand, a convenient method for CuCl2-catalyzed arylation of imidazo[1,2-b]thiazoles and thiazoles with aryl iodides under mild reaction conditions is described. Preliminary mechanistic studies of this arylation involving a formal Cu(I) to Cu(0) and Cu(II) route by convergent disproportionation of the copper mediator are also reported. Copyright © 2015 John Wiley & Sons, Ltd.
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