syn-Selective Asymmetric Mannich Reaction of Sulfonyl Imines with Iminoesters Catalyzed by the N,N,N-Tridentate Bis(imidazolidine)pyridine (PyBidine)–Cu(OTf)2 Complex

2012 
The reaction is effective for the N-tosyl and N-4-nosylimines but can not be applied to the 2-nosylimines.
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