Method for producing polyalkylene glycol derivative having amino group at terminal, and polymerization initiator used in the method, and alcohol compound that serve as starting material for polymerization initiator

2015 
PROBLEM TO BE SOLVED: To provide a method for producing a narrow disperse and highly pure polyalkylene glycol derivative having an amino group at a terminal thereof and to provide a polymerization initiator used in the method, and a precursor thereof.SOLUTION: There are provided a method for producing a polyalkylene glycol derivative having an amino group at a terminal thereof, in which a compound represented by general formula (I) is used as a polymerization initiator, a compound represented by general formula (I) and a precursor thereof. In the formula, Rand Reach independently represent a protective group for an amino group, or one of the Rand the Rrepresents H and the other of the Rand the Rrepresents a protective group for an amino group, or the Rand the Rrepresent a cyclic protective group by being linked with each other to form a ring; Rrepresents a linear, branched or cyclic hydrocarbon group having 1 to 6 carbon atoms; Rrepresents a single bond or a 1 to 20 C linear, branched or cyclic hydrocarbon group that may include hetero atoms; a total number of carbon atoms of the Rand the R(or a total number of carbon atoms and hetero atoms) is 4 or more; and M represents an alkali metal.SELECTED DRAWING: None
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