Austauschreaktionen an komplexgebundenen liganden von elementen der IV. Hauptgruppe : II. Aminolyse von cyclopentadienyl-dicarbonyl-trichlorsilyl-eisen

Zusammenfassung The reaction of CpFe(CO) 2 SiCl 3 with amines in benzene or in pure amine give the complex compounds CpFe(CO) 2 SiCl 3− x (NRR′) x (R = alkyl, aryl; R′ = H, alkyl; x = 1–3), x depending on the basicity of the amine and, far more important, on the steric requirements of the amine. The new compounds are characterized by IR, NMR, and mass spectra.