Anion-exchange separation and spectrophotometric determination of molybdenum and tungsten in silicate rocks

Abstract A combined ion-exchange spectrophotometric method has been developed for the determination of molybdenum and tungsten in silicate rocks. After the decomposition of samples with a mixture of sulphuric, nitric and hydrofluoric acids, traces of molybdenum and tungsten are separated from other elements by anion-exchange in acid sulphate media containing hydrogen peroxide. The adsorbed molybdenum and tungsten can easily be stripped from the column by elution with sodium hydroxide-sodium chloride solution. The adsorption and desorption steps provide selective concentration of molybdenum and tungsten, allowing the simultaneous spectrophotometric determination of the two metals with dithiol. Results on the quantitative determination of molybdenum and tungsten in the U.S. Geological Survey standard samples are included.