X-ray irradiation-induced ionization of CdS1−xSex nanocrystals embedded in borosilicate glass
2010
Optical absorption spectra of x-ray irradiated CdS1−xSex nanocrystals embedded in a borosilicate glass matrix are studied. The observed transformation of the confinement-related features in the spectra is related to the x-ray-induced negative ionization of the nanocrystals with charge transfer across the nanocrystal/matrix interface. The radiation-induced changes and their relaxation upon postirradiation storage as a function of nanocrystal size and composition are discussed.
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