Reinforcing Germanium Electrode with Polymer Matrix Decoration for Long Cycle Life Rechargeable Lithium Ion Batteries
2017
Germanium is a promising anode material for lithium ion batteries because of its high theoretical specific capacity and low operation voltage. However, a significant challenge in using Ge-based anodes is the large volume variation during cycling that causes pulverization and capacity fade. Despite intense studies in the past decade, unsatisfactory cycling stability of the Ge-based electrodes still impedes their widespread applications. In this study, we demonstrate a high-performance electrode through the synergistic combination of a high-capacity Ge film grown on a three-dimensional current collector and an in situ formed poly(vinylidene fluoride)–hexafluoropropene/SiO2 protective layer. Specifically, the polymer matrix is in continuous contact with the surface of the Ge shell, which provides improved mechanical and ionic transport properties. As a highlight, we present impressive cycling stability over 3000 cycles at 1 C rate with a capacity retention as high as 95.7%. Furthermore, the LiCoO2–Ge full ba...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
79
References
16
Citations
NaN
KQI