The Baylis–Hillman acetates as a source of ambiphilic molecules: a simple synthesis of 1,3-thiazinane-2-thione frameworks

Abstract Ambiphilic molecules (allylamines 1 ), easily accessible from the Baylis–Hillman acetates, have been effectively utilized for stereoselective synthesis of c is -5,6-disubstituted-1,3-thiazinane-2-thione derivatives ( 2 ) via the reaction with carbon disulfide as a bridging partner.