Studium přípravy a struktury bifunkčních β-diketiminátů

Within the scope of this thesis, the set of three bifunctional s-diketimines and one bifunctional s-enaminoketone has been prepared. These compounds have been used as ligands for preparation of their complexes with lithium and potassium ionts. The interest has been focused on studying of reactivity of these complexes with selected metal compounds. The prepared set of compounds as well as major number of products was identified by NMR spectroscopy. Their structure was studied by multinuclear NMR spectroscopy in solution of various solvents, and X-ray diffraction techniques in the solid state, respectively. The structure of four compounds, namely two s-diketimines, one s-diketimine hydrochloride and complex of s-enaminoketonate with lithium having Li4O4 asymetric heterocubane structure has been determined by using X-ray diffraction on single crystalline material.