Novel [2]pseudorotaxanes constructed by self-assembly of bis-urea-functionalized pillar[5]arene and linear alkyl dicarboxylates
2012
A bis-urea-functionalized pillar[5]arene has been synthesized and shown to form [2]pseudorotaxanes spontaneously with linear alkyl dicarboxylates in highly polar solvent DMSO, in which the hydrogen bonding interactions between the bis-urea hydrogens and dicarboxylate oxygens play an important role in stabilizing the novel [2]pseudorotaxanes alongside C–H⋯π interactions.
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