The Environment-Dependent Behavior of the Blatter Radical at the Metal-Molecule Interface
2019
Stable organic radicals have potential applications for building organic spintronic devices. To fulfill this potential, the interface between organic radicals and metal electrodes must be well characterized. Here, through a combined effort that includes synthesis, scanning tunneling microscopy, X-ray spectroscopy and single-molecule conductance measurements, we comprehensively probe the electronic interaction between gold metal electrodes and a benchtop stable radical – the Blatter radical. We find that in spite of its open-shell character and having a half filled orbital close to the Fermi level, the radical is stable on a gold substrate under ultra-high vacuum. We observe a Kondo resonance arising from the radical and spectroscopic signatures from its half-filled orbitals. By contrast, in solution-based single molecule conductance measurements, the radical character is lost through oxidation, with charge transfer occurring from the molecule to metal. Our experiments show that the stability of radical states can be very sensitive to the environment around the molecule.
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