Tri­chloro­(perdeuteroaceto­nitrile)­bis­(tri­phenyl­phosphine)­rhodium(III)

William Clegg,Andrew J. Scott,Nicholas C. Norman,Edward G. Robins,George R. Whittell

Trichloro(perdeuteroacetonitrile)bis(triphenylphosphine)rhodium(III)

2002

William Clegg
Andrew J. Scott
Nicholas C. Norman
Edward G. Robins
George R. Whittell

The title complex, [RhCl3(PPh3)2(NCCD3)], crystallizes with two independent, but essentially identical, molecules in the asymmetric unit. Rh is octahedrally coordinated by three mer-chloro ligands, two mutually trans-phosphines, and a molecule of the NMR solvent perdeuteroacetonitrile.

Keywords:

Rhodium
Nitrile
Stereochemistry
Solvent
Biochemistry
Chemistry
Phosphine
Ligand
Inorganic chemistry
Polymer chemistry

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Tri­chloro­(perdeuteroaceto­nitrile)­bis­(tri­phenyl­phosphine)­rhodium(III)

Trichloro(perdeuteroacetonitrile)bis(triphenylphosphine)rhodium(III)