Nitrogen- and Boron-Doped Carbon Nanotube Electrodes in a Thermo-Electrochemical Cell
2012
We explore the prospects of using doped carbon nanotube (CNT) electrodes to increase the output power of thermo-electrochemical cells (TECs). CNT buckypaper electrodes doped with nitrogen and boron were characterized using cyclic voltammetry, impedance spectroscopy, and TEC test with potassium ferri/ferrocyanide electrolyte. Both doping states increased the electrochemically active surface area of CNT electrodes. Electrostatic interactions with potassium ions altered the charge transfer kinetics for doped CNT electrodes;yet,thesymmetryofthechargetransferremainedapproximatelyequaltothatofpristineCNTs.InTECtest,accumulation of potassium ions at doped CNT electrodes was found to reduce short-circuit current. ©2012 The Electrochemical Society. [DOI: 10.1149/2.043205jes] All rights reserved.
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