Orientational ordering in methane condensates in mesoporous SiO2 modifications at low temperatures
2000
The rotational spectra of CH 4 at low temperatures have been used to investigate the disordering influence of a restricted geometry on the orientational structure of methane condensates in silicagels and Controlled Pore Glasses. A cross-over from complete orientational disorder to the partially ordered phase II of pure methane was observed with increasing pore diameter d at d ∼120 A.
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