Formation of Adamantane‐Like Structures by Reaction of Titanocene Fluorides with an Iminoalane
1998
Fluorine–nitrogen metathesis in the reaction of a cyclic iminoalane with titanocene fluorides results in unexpected cage compounds. Treatment of one of these compounds with diethyl ether leads to 1, which contains a titanium–nitrogen double bond stabilized intramolecularly by fluorine.
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