The preparation of Co9S8 and CoS2 nanoparticles by a high energy ball-milling method and their electrochemical hydrogen storage properties
2014
Abstract Two different Co–S compounds with enhanced hydrogen storage properties, Co 9 S 8 and CoS 2 , were prepared by ball-milling mixtures of Co metal and S powder. X-ray diffractometry, scanning electron microscopy and transmission electron microscopy were used to show that specific molar ratios of Co:S and ball-milling speeds and times result in pure Co 9 S 8 and CoS 2 , thus overcoming a long-standing inability to obtain pure Co–S compounds via ball-milling. A galvanostatic charge–discharge process and cyclic voltammetry measurements showed that the as-obtained Co 9 S 8 and CoS 2 nanoparticles have enhanced electrochemical hydrogen storage capacities of 1.79 and 1.57 wt% hydrogen, respectively, which are higher than those previously reported. In addition, based on the corresponding X-ray photoelectron spectroscopy and cyclic voltammetry measurements, a new electrochemical hydrogen storage mechanism for the two Co–S compounds was proposed and discussed.
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