Spectral studies of the mechanism of oxidation of Cp2Fe by ozone

R. G. Bulgakov,L. I. Sharapova,G. L. Sharipov,G. G. Bikbaeva

Spectral studies of the mechanism of oxidation of Cp2Fe by ozone

1999

R. G. Bulgakov
L. I. Sharapova
G. L. Sharipov
G. G. Bikbaeva

The mechanism of oxidation of Cp2Fe by ozone in CCl4 was studied by chemiluminescence (CL), photoluminescence, IR, UV, and NMR spectral techniques, Ozone attacks Cp2Fe at the Fe−C and C=C bonds to form peroxides CpOOFe, CpFeOOH, triplet (3 nπ*) ketones (CL emitters), and organic acids.

Keywords:

Ferrocene
Chemiluminescence
Photoluminescence
Organic chemistry
Organic acid
Photochemistry
Chemistry
Inorganic chemistry
Ozone

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