High-performance Li-Se battery cathode based on CoSe2-porous carbon composites
2018
Abstract The sluggish redox kinetics and dissolution of polyselenide result in severe capacity attenuation of lithium-selenium (Li-Se) batteries, thus significantly limiting its practical application. In this study, we developed a facile annealing procedure to prepare CoSe 2 -porous carbon composites (CoSe 2 -PC) as a high-performance cathode material. The formation of CoSe 2 nanoparticles in the carbon matrix was confirmed by high resolution transmission electron spectroscopy (HRTEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) measurements. Se@CoSe 2 -PC achieved a reversible capacity up to 408 mAh·g −1 after 100 charge-discharge cycles at the current rate of 1 C, a performance much higher than that of porous carbon alone. The catalytic effect of CoSe 2 on the redox reaction dynamics of polyselenide was examined by cyclic voltammetric measurements using a symmetrical cell of Se@CoSe 2 -PC in the presence and absence of the polyselenide in the electrolyte, and this likely accounts for the high specific capacity and superior cycle performance of Se@CoSe 2 -PC based Li-Se batteries. Results from this work may open up a door for suppressing the dissolution of polyselenide and eventually realize Li-Se batteries of high capacity and cycle stability.
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