Next nearest neighbor effect in chromite
1988
In this paper the Mossbauer spectra of a chromite at 140K 200K and 298K were measured. Next nearest neighbor effects were used to explain the spectra of the chromite, and multiple doublets of Fe2+ ions on the A sites were caused by the different cation combinations on 12 next nearest neighbor B sites. The quandrupole splitting of each of mult iple Fe2+ doublets decreases with increasing temperature.
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