Studies on the Selectivity Between Glycosylation and Intermolecular Aglycone Transfer of Thioglucoside in Synthesis of Lactose Derivatives.

Marie Kato,Go Hirai,Mikiko Sodeoka

Studies on the Selectivity Between Glycosylation and Intermolecular Aglycone Transfer of Thioglucoside in Synthesis of Lactose Derivatives.

2012

Marie Kato
Go Hirai
Mikiko Sodeoka

In the reaction with the thioglycoside acceptor (II), electron-donating groups on the galactose donor (I) can prevent the aglycone-transfer (AGT) reaction.

Keywords:

Acceptor
Selectivity
Galactose
Lactose
Aglycone
Glycosylation
Chemistry
Organic chemistry
Intermolecular force

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