Combination of a Binaphthol-Derived Phosphite and a C1-Symmetric Phosphinamine Generates Heteroleptic Catalysts in Rh- and Pd-Mediated Reactions.

Heteroleptic complexes, formed selectively by using a 1 : 1 combination of a σ-donor and a π-acceptor ligand, are involved in Rh- and Pd-catalysed reactions.