Bis(chloro-acetato-κO,O')bis-(2-fluoro-benzyl-κC)tin(IV).
2011
In the title complex, [Sn(C2H2ClO2)2(C7H6F)2], the SnIV atom is located on a twofold rotation axis and forms a strongly distorted trans-octahedral geometry. The equatorial plane is defined by two chelating chloroacetate ligands with asymmetrical Sn—O bond lengths, while the axial positions are occupied by the C atoms of two 2-fluorobenzyl groups. In the crystal, infinite chains in the [010] direction are formed through intermolecular Sn⋯O interactions [Sn⋯O separation = 3.682 (3) A].
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