Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts

Two stereoisomers of pentacoordinate iridium(III) hydridochloride with triptycene-based PC(sp3)P pincer ligand (1,8-bis(diisopropylphosphino)triptycene), 1 and 2, differ by the orientation of hydri...