Relaxation-speed crossover in anharmonic potentials

In a recent paper [Phys. Rev. Lett. 125, 110602 (2020)], thermal relaxation was observed to occur faster from cold to hot (heating) than from hot to cold (cooling). Here we show that overdamped diffusion in anharmonic single-well potentials generically allows for both faster heating and faster cooling, depending on the initial temperatures and on the potential's degree of anharmonicity. We draw a relaxation-speed phase diagram that localises the different behaviours in parameter space. In addition to faster-heating and faster-cooling regions, we identify a crossover region in the phase diagram, where heating is initially slower but asymptotically faster than cooling.