Diurnal variability of total column NO 2 measured using direct solar and lunar spectra over Table Mountain, California (34.38° N)

Abstract. A full diurnal measurement of total column NO2 has been made over the Jet Propulsion Laboratory’s Table Mountain Facility (TMF) located in the mountains above Los Angeles, California, USA (2.286 km above mean sea level, 34.38° N, 117.68° W). During a representative week in October 2018, a grating spectrometer measured the telluric NO2 absorptions in direct solar and lunar spectra. The total column NO2 is retrieved using a model-based minimum-amount Langley extrapolation, which enables us to accurately treat the non-constant NO2 diurnal cycle abundance and the effects of pollution near the measurement site. The measured 24-hour cycle of total column NO2 on clean days agrees with a 1-D photochemical model calculation, including the monotonic changes during daytime and nighttime due to the exchange with the N2O5 reservoir and the abrupt changes at sunrise and sunset due to the activation or deactivation of the NO2 photodissociation. The observed daytime NO2 increasing rate is (1.29 ± 0.30)×1014 cm−2 h−1. The total column NO2 in one of the afternoons during the measurement period was much higher than the model simulation, implying the influence of urban pollution from nearby cities. A 24-hour back-trajectory analysis shows that the wind first came from inland in the northeast and reached the southern Los Angeles before it turned northeast and finally arrived TMF, allowing it to pick up pollutants from Riverside County, Orange County, and Downtown Los Angeles.