An experimentally based description of the ground-state wavefunction for two weakly coupled electrons by photoelectron spectroscopy and magnetic susceptibility measurements

It is possible to extract values for the transfer energy, t, and the Coulomb interaction, U, in hydrogen-like systems from a combination of photoelectron and magnetic data, as both the form of the photoelectron spectrum and the exchange splitting are determined by these quantities. This procedure is used to evaluate the ground-state wavefunction for the two weakly coupled Ti 3d electrons in (C10H8)(C5H5)2Ti2Cl2.