Scalable route to Electroactive and Light active Perylene diimide dye polymer Binder for Li ion Batteries

Developing multifunctional polymeric binders is key to the design of energy storage technologies with value-added fea-tures. We report that a multigram scale synthesis of perylene diimide polymer (PPDI), from a single batch via polymer analogous reaction route, yields high molecular weight polymers with suitable thermal stability and minimized solubility in electrolytes, potentially leading to improved binding affinity toward electrode particles. Further, it develops strategies for designing copolymers with virtually any desired composition via a subsequent grafting, leading to purpose-built binders. PPDI dye as both binder and electroactive additive in lithium half-cells using lithium iron phosphate exhibit good electrochemical performance.